Photoisomerization of azobenzenes isolated in cryogenic matrices
نویسندگان
چکیده
منابع مشابه
Photoisomerization of azobenzenes isolated in cryogenic matrices.
2,2'-Dihydroxyazobenzene (DAB), 2,2'-azotoluene (AT) and azobenzene (AB) were isolated in argon and xenon matrices and their molecular structures and photochemical transformations were characterized by infrared spectroscopy and theoretical calculations. All these compounds can adopt the E and Z isomeric forms around the central CNNC moiety, which can be enriched by several conformational and ta...
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Diketene (C(4)H(4)O(2)) monomers were isolated in cryogenic Ar (15 K) and Xe (30 K) matrices. The infrared (IR) spectra of the freshly deposited matrices show that diketene monomers exclusively adopt the 4-methylene-oxetan-2-one form. In situ photochemical transformations of diketene were induced by tunable UV laser light. Diketene was found to be photostable when exposed to near-UV irradiation...
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Both cis and trans isomers of FCSF were generated by irradiation of Ar matrix isolated F(2)CS at 16 K with an ArF excimer laser (lambda = 193 nm).
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3-Furaldehyde (3FA) was isolated in an argon matrix at 12 K and studied using FTIR spectroscopy and quantum chemistry. The molecule has two conformers, with trans and cis orientation of the O=C-C=C dihedral angle. At the B3LYP/6-311++G(d,p) level of theory, the trans form was computed to be ca. 4 kJ mol(-1) more stable than the cis form. The relative stability of the two conformers was explaine...
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The article presents the mathematical models and the results obtained has the numerical modelling of the thermal status of the electrical leads isolated for cryogenic applications. Model them mathematics are based on the equation of thermal conduction 1D and 2D. For the numerical resolution of the thermal conduction equation one uses the finite volumes method. The elaborate program permits to g...
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2016
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c6cp02583h